Sign in to the your Duo account, left click on your user icon, then select the option "Edit Profile";
You will be presented with your user account details, scroll down to the end of these details, then click on the button
;

A window titled "Add a Passkey" will now open, click
;

You will now be asked how the passkey will be created, click "Save another way";

Next select "Windows hello or external security key";

When asked where to save this passkey, select the option "Security Key", then click
;

You are now notified that access to google will be prepared with your Fido2 security key - click
to proceed to the next step;

Next you are asked for permission for the site to access your Fido2 key, insert the key into an available USB port then click
;

You will now be asked to touch the button on your key (if your model has a fingerprint reader you may be asked to provide a finger swipe instead);

Provided you press the button on the Fido2 key in the allowed time, the passkey details will be stored on your Fido2 key, and you will be presented with the following confirmation;

Click "OK", and the FIIDO2 key will be registered with Duo, and you will be shown confirmation that the passkey has been added;

Click
, and you Fido key will be ready to be used when you next log in to Duo.